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Tłumaczenia dla hasła „cyclization“ w rosyjsko » angielski słowniku

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angielski
Metal-catalyzed cyclization reactions usually require mildly basic conditions, and substrates must be chosen to avoid -hydride elimination.
en.wikipedia.org
The cyclization of -epoxy-1-nitriles provides an interesting example of how stereoelectronic factors may override steric factors in intramolecular substitution reactions.
en.wikipedia.org
Both lanosterol and cycloartenol are derived via cyclization of the triterpenoid squalene.
en.wikipedia.org
A classic example is the cyclization of geranyl pyrophosphate to form limonene.
en.wikipedia.org
The dimethylallyl group in 7 then undergoes cyclization with the phenol group to give 8.
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In this pathway, vinblastine is constructed by a series of cyclization and coupling reactions which create the required stereochemistry.
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Other applications include use in alkylation reactions and as a catalyst component in linear oligomerization and cyclization of unsaturated hydrocarbons.
en.wikipedia.org
The resulting o-benzoylbenzoic acid then undergoes cyclization, forming anthraquinone.
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Approaches to this synthesis are diverse, and include central steps such as annululation, olefin metathesis, radical cyclization, and trapping reactions.
en.wikipedia.org
The polyketide chain produced is electronically capable to go through a lactonization and a diels alder cyclization, as shown below.
en.wikipedia.org

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